Design principles for polyethylene deconstruction Scientists established mechanistic role of metal oxide support on the catalytic deconstruction of polyolefins under H2.
Reactive separations improve polymer upcycling Reactive separation provides a complementary strategy to catalyst design to achieve selective conversion of polyolefins to upcycled liquids and avoiding the formation of light gases.
Chemo-Microbial Conversion of Polyethylene Wasteinto Silk-Protein We report the development of a new strain of Pseudomonas bacteria capable of converting depolymerized polyethylene into high value recombinant protein products.
Mass Transfer in Catalytic Depolymerization: Serendipitous Processivity in Stagnant and Stirred Melts The study predicts the effects of diffusion limitations on co-reactant transport to the catalyst and on chain egress after scission.
Microwave-Assisted Synthesis of SrTiO3 Nanocuboids without TiCl4 A microwave-assisted heating method was developed to afford 20+ g STO samples at milder conditions than previously attainable without TiCl4 and in only water.
Adsorption and Mobility of Polymers in Long Nanopores: From Non-eq Stat Mech to 2D-NMR This research enables quantitative estimates of polymer reptation diffusivity and polymer-wall interactions in silicananopores.
Scalable, Solution Phase Deposition of Nanoparticles for the Catalytic Hydrogenolysis of Plastic Waste A deposition method for Pt onto SrTiO3 (STO; Pt/STO) supports was developed that facilitates synthetic scale-up and retains the precision of atomic layer deposition.
Coarse-Grained Modeling of Polymer Cleavage Within a Porous Catalytic Support Results of this research offer a mechanistic explanation for an experimentally observed product distribution trend related to a tunable physical parameter of a catalytic architecture for plastics’ upcycling.
Molecular Weight Evolution in Polymer Upcycling: Extracting Rates and Identifying Mechanistic Signatures This research resulted in development of a framework to formulate and solve coupled bulk population balances, bulk species balances, and surface-adsorbed population balances.
Recyclable Polyethylene-Like Polymer From Plastic Jug This work highlights the transformation of plastic waste using catalytic transformations to obtain a new HDPE-like polymer that maintains similar thermal and mechanical properties to the original material.