Research Highlights

Characterizing the Solvation Interactions of Choline Chloride-based Deep Eutectic Solvents Employed in Separations

Solvation properties of choline chloride-based deep eutectic solvents (DESs) were thoroughly characterized using gas chromatography for the first time.

Solvent visuals and plot of hydrogen bond basicity versus dispersive-type interactions

Using a Chromatographic Pseudophase Model to Elucidate the Mechanism of Olefin Separation by Silver(I) Ions in Ionic Liquids

A three-phase chromatographic model treating silver(I) ions as a pseudophase is constructed and applied to investigate the olefin separation mechanism in silver(I) salt/ionic liquid (IL) mixtures. The partition coefficients and the values for enthalpy, entropy, and free energy of solvation of analytes are determined using the model.

Silver(I) ion-olefin interaction schematic and graph

3D Structures of Single Site Catalysts From the Ground Up

A robust method for determining the 3D structures of arbitrary silica-supported molecules is developed.

Visual 3D structures of the grafted Sc amidinate complex

Mechanochemical extraction of lithium at low temperature (MELLT) from chemical-grade domestic α-Spodumenes

CMI researchers at the Ames Laboratory conducted the activity for this highlight

Characterizing Olefin Selectivity and Stability of Silver Salts in Ionic Liquids Using Inverse Gas Chromatography

Long-term olefin selectivity offered by silver salt/ionic liquid (IL) mixtures is evaluated by inverse gas chromatography (IGC). The approach enables the separation media to be examined under various environmental conditions (e.g., different temperatures and gas streams) typically encountered when performing olefin separations.

Graphic with experimental scheme and retention of olefin and paraffin probes data chart.

Elucidating the Role of Hydrogen Bond Donor and Acceptor on Solvation in Deep Eutectic Solvents

Deep eutectic solvents comprised of ammonium/phosphonium salts and carboxylic acids have been characterized by inverse gas chromatography to understand their solvation interactions. Solute-solvent interactions are beneficial in understanding the performance of DESs in various chemical separations and catalysis.

Complex magnetic energy landscapes in topological magnets

Economical new chelator delivers binding selectivity for rare earths

CMI researchers at Oak Ridge National Laboratory and Ames Laboratory conducted the activity for this highlight

diagram of X-ray crystal structure of acyclopa complexed to the large lanthanum (La) ion. Hydrogen atoms, counteranions, and solvent molecules are omitted for clarity.

SmFeN as a cost-effective high-performance magnet

CMI researchers at Ames Laboratory conducted the activity for this highlight

Manufacturing process for permanent magnet review articles

CMI researchers at Ames Laboratory, Lawrence Livermore National Laboratory and Oak Ridge National Laboratory conducted the activity for this highlight