The 15 MGOe gap magnet without critical rare earths CMI researchers create the 15 MGOe gap magnet without critical rare earths
Direct reduction slashes Al-Ce alloy cost Successful manufacturing demonstration of the production of Al-Ce alloy using direct reduction of commercial-grade cerium carbonate and oxide
Diffraction paradox reveals perfection in graphene A broad diffraction component observed in electron diffraction of graphene reveals the degree of structural perfection. The broadening is due to electron confinement within the graphene layer, with single layer precision over the mesoscale.
Catalyzing the Transformation of Waste Plastics into Value-Added Products Selective catalytic hydrogenolysis provides high-quality, value-added liquid products from polyethylene
A Second Life for Polyolefins as Biodegradable Surfactants This catalytic deconstruction of polyolefins, using Earth-abundant Zr catalyst and Al reactants, into valuable, biodegradable surfactant and detergent precursors, provides an economically and environmentally sustainable end-of-life for single-use plastics.
Competing orders and role of fluctuations in FeSe Above a critical pressure associated with the onset of magnetic order, superconducting and magnetic fluctuations exist over a wide temperature range above their respective bulk transition temperatures. Superconductivity in FeSe under pressure is bulk and competes with magnetism; measurements reveal fluctuations of superconductivity and magnetism likely due to their competing nature similar to other high-Tc superconductors.
Probing the Microstructure of Poly(Cyclosilane) The microstructure of poly(cyclosilane) was determined by 29Si solid-state NMR spectroscopy and density-functional theory calculations. The NMR and DFT calculation structure determination protocol will be useful to resolve the molecular structure of silicon-based materials, enabling structure-function relationships to be established.
Phase diagram of the van der Waals ferromagnet VI3 under pressure Van der Waals (vdW) materials are versatile systems for the study of magnetism in low dimensions. Motivated by the potential tunability of the new vdW ferromagnet VI3, a microscopic and thermodynamic study on bulk single crystals were performed under hydrostatic pressure using new techniques developed at Ames Laboratory.
The Surface Structure of Semiconductor Nanoparticles Revealed By mixing precipitated nanoparticles (NP) with boron nitride (BN) a 9-fold improvement in DNP NMR sensitivity was realized compared to established DNP protocols. This new protocol enables challenging 2D NMR experiments that reveal the structure and connectivity of atoms in a variety of semiconductor NP systems.
![(top) 2-d diffraction pattern of graphene grown on SiC shows sharp spots on a very broad background around the (00) and G(10) spots. (bottom) 1-d scan of the (00) spot along [12 ̅10] shows the broad component with unusually large FWHM that unexpectedly correlates to forming a highly uniform film.](/sites/default/files/styles/max_1300x1300/public/2019-12/Diffraction%20paradox%20reveals%20perfection%20in%20graphene.PNG?itok=-zHVQ6X1)
