Group 4 Metallocenes Supported on Sulfated Zirconium Oxide Catalyze Benzene C‒H Borylation
This discovery proves that early transition metals can effectively perform challenging C-H bond functionalization, rivaling established, expensive late-transition metal (Ir, Rh) systems. It opens new paths and design principles for strong-bond activation using highly electrophilic, surface-stabilized active sites in alterative to critical noble metals.