Production of Dy metal from sodium-lean fluoride feedstock

CMI Highlight: Production of Dy metal from sodium-lean fluoride feedstock

Powder X-ray diffraction patterns of Na(lean)-Dy-F samples prepared in fresh and wastewater
Powder X-ray diffraction patterns of Na(lean)-Dy-F samples prepared in fresh and wastewater

CMI researchers at Ames National Laboratory and Terves conducted the research for this highlight

Innovation 

  • The sodium-lean fluoride precursor was synthesized through an ambient-temperature aqueous-phase reaction, without using or generating HF.
  • Dy metal is produced via metallothermic reduction of sodium-lean dysprosium fluoride salts.

Achievement
Successfully produced about ~420 g of Na(lean)‑Dy‑F by scaling the process threefold through reuse of the same water across three batches, reducing NaF usage by ~40% while achieving high Dy metal purity (≥99.6%).

Significance and Impact

  • Demonstrated 115 g-scale production of rare earth metal (Dy) from sodium-lean feedstock without using or generating hazardous chemicals.
  • Supports domestic Dy metal for NdFeB permanent magnet production.

Hub Target Addressed 
Energy-efficient rare earth metals production.
 

Cast dysprosium metal pieces (~115g) produced via calciothermic reduction of Na‑lean dysprosium fluoride
Cast dysprosium metal pieces (~115g) produced via calciothermic reduction of Na‑lean dysprosium fluoride