Analysis of Nanostructuring in High Figure-of-Merit Ag1-xPbmSbTe2+m Thermoelectric Materials

TitleAnalysis of Nanostructuring in High Figure-of-Merit Ag1-xPbmSbTe2+m Thermoelectric Materials
Publication TypeJournal Article
Year of Publication2009
AuthorsCook BA, Kramer MJ, Harringa JL, Khan M, Chung DY, Kanatzidis MG
Journal TitleAdvanced Functional Materials
Date Published04/23
ISBN Number1616-301X
Accession NumberISI:000265855700016
Keywordsagpbmsbte2+m, devices, glasses, performance, quantum-dot superlattice, silicon-germanium alloys, thermal-conductivity, transport-properties

Thermoelectric materials. based on. quaternary compounds Ag1-xPbmSbTe2+m exhibit high dimensionless figure-of-merit values, ranging from 1.5 to 1.7 at 700 K. The primary factor contributing to the High figure of merit is a low lattice thermal conductivity, achieved through nanostructuring during melt solidification. As a.consequence of nucleation and growth of a second phase; coherent nanoscale inclusions form throughout the material, which are believed to result in scattering of acoustic phonons while causing only minimal scattering of charge carriers. Here, characterization of the nanosized inclusions in Ag0.53Pb18Sb1.2Te20 that shows a strong tendency for crystallographic orientation along the {001} planes, with a high degree of lattice strain at the interface, consistent with a coherent interfacial boundary is reported. The inclusions are enriched in Ag relative to the matrix, and seem to adopt a cubic, 96 atom per unit cell Ag2Te phase based on the Ti2Ni type structure. In-situ high-temperature synchrotron radiation diffraction studies indicated that the inclusions remain thermally stable to at least 800 K.

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