Recent developments in OLED-Based chemical and biological sensors - art. no. 665906

TitleRecent developments in OLED-Based chemical and biological sensors - art. no. 665906
Publication TypeBook Chapter
Year of Publication2007
AuthorsShinar J, Zhou Z, Cai Y, Shinar R
EditorShinar R, Malliaras GG
Book TitleOrganic-Based Chemical and Biological Sensors
CityBellingham
PublisherSpie-Int Soc Optical Engineering
Volume6659
Pages65906-65906
Series TitleProceedings of the Society of Photo-Optical Instrumentation Engineers (Spie)
ISBN Number0277-786X978-0-8194-6807
Accession NumberISI:000251493200003
KeywordsCOMBINATORIAL FABRICATION, DISSOLVED-OXYGEN, ethanol sensor, EXCITATION SOURCE, glucose sensor, IMMUNOASSAYS, lactate sensor, LIGHT-EMITTING DEVICES, MULTIANALYTE, multianalyte sensor, OLED, organic light-emitting device, oxygen sensor, PHOTOLUMINESCENCE
Abstract

Recent developments in the structurally integrated OLED-based platform of luminescent chemical and biological sensors are reviewed. In this platform, an array of OLED pixels, which is structurally integrated with the sensing elements, is used as the photoluminescence (PL) excitation source. The structural integration is achieved by fabricating the OLED array and the sensing element on opposite sides of a common glass substrate or on two glass substrates that are attached back-to-back. As it does not require optical fibers, lens, or mirrors, it results in a uniquely simple, low-cost, and potentially rugged geometry. The recent developments on this platform include the following: (1) Enhancing the performance of gas-phase and dissolved oxygen sensors. This is achieved by (a) incorporating high-dielectric TiO2 nanoparticles in the oxygen-sensitive Pt and Pd octaethylporphyrin (PtOEP and PdOEP, respectively)doped polystyrene (PS) sensor films, and (b) embedding the oxygen-sensitive dyes in a matrix of polymer blends such as PS:polydimethylsiloxane (PDMS). (2) Developing sensor arrays for simultaneous detection of multiple serum analytes, including oxygen, glucose, lactate, and alcohol. The sensing element for each analyte consists of a PtOEP-doped PS oxygen sensor, and a solution containing the oxidase enzyme specific to the analyte. Each sensing element is coupled to two individually addressable OLED pixels and a Si photodiode photodetector (PD). (3) Enhancing the integration of the platform, whereby a PD array is also structurally integrated with the OLED array and sensing elements. This enhanced integration is achieved by fabricating an array of amorphous or nanocrystalline Si-based PDs, followed by fabrication of the OLED pixels in the gaps between these Si PDs.