Elemental composition of solid deposit determined by EDS

Characterization of electrolytically produced Ga-REE alloy

Product formed in cathode compartment of electrolytic cell
Product formed in cathode compartment of electrolytic cell 

CMI researchers at Idaho National Laboratory conducted the activity for this highlight

Innovation 
Produce rare earth alloy products from aqueous solution, at low temperatures (<100°C).

Achievement 

  • Powders produced by electrochemical reduction of Pr3+ by a Ga cathode at 40°C were examined by scanning electron microscopy and energy dispersive X-ray spectroscopy (SEM-EDS).
  • Powders heterogeneous, but EDS elemental analysis showed consistently that Pr and Ga were at least partially reduced.

Significance and impact

  • Approach offers a way to produce REE alloys with low energy inputs. 
  • Ability to characterize products enables process optimization.
  • Alloys to be evaluated as potential feeder anodes for low-temperature REE metal production in non-aqueous electrolytes.

Hub target addressed 
Recovery and conversion into high value end-products.
 

Elemental composition of solid deposit determined by EDS
Elemental composition of solid deposit determined by EDS