Unlocking cobalt from cobaltiferous pyrite by inert roasting

 Reaction Scheme Used for Thermodynamic Modeling to Evaluate Pyrite Decomposition
Reaction Scheme Used for Thermodynamic Modeling to Evaluate Pyrite Decomposition

CMI researchers at Colorado School of Mines conducted the research for this highlight

Innovation 

  • Inert roasting was used as a selective desulfurization step to upgrade cobaltiferous pyrite, where Co is structurally hosted within the pyrite lattice.
  • The treatment increased cobalt (Co) grades through sulfur removal while transforming the sulfide matrix into a calcine for downstream magnetic separation.

Achievement

  • Inert roasting increased cobalt grades by up to 15% with negligible cobalt loss and high-purity sulfur co-production.
  • Magnetic separation of the roasted calcine yielded a concentrate with 2.09% Co at 82.5% recovery, a 16-74% improvement over prior baselines.

Significance and Impact

  • Publication describes a pathway to upgrade cobaltiferous pyrite feedstocks beyond conventional flotation limits.
  • Supports improved Co recovery from complex domestic sulfide resources.

Hub Target Addressed 
Recovering critical materials from unconventional sources.

Backscatter image from SEM (left) and AMICS (right) segmented map of decomposed samples after 15 min at 650 C and 33 STD mL/min.
Backscatter image from SEM (left) and AMICS (right) segmented map of decomposed samples after 15 min at 650 C and 33 STD mL/min.