REE recovery and purification from phosphogypsum leachate

Bank of centrifugal contactors used for the flowsheet demonstration at PNNL
Bank of centrifugal contactors used for the flowsheet demonstration at PNNL

CMI researchers at Florida Industrial & Phosphate Research Institute (FIPR) and the Pacific Northwest National Laboratory conducted the research for this highlight

Innovation 
Phosphogypsum (PG), a high-volume waste byproduct of fertilizer production from mined phosphate rock, represents an untapped secondary resource for critical rare earth elements (REEs). The CMI team has developed a new process that selectively recovers REEs from PG while simultaneously converting the residual material into cement as a value-added product.

Achievement
Developed a novel diglycolamide (DGA)-based solvent extraction flowsheet for bulk recovery and purification of REEs from PG (Riverview plant, Mosaic Co) leachate and performed first demonstration using counter-current centrifugal contactors.

Significance and Impact

  • The new process achieves 99% recovery of critical REEs from PG leachate. 
  • It enables in situ generation of two product streams: LREE- and HREE-enriched liquid concentrates.
  • The developed flowsheet is fully compatible with centrifugal contactors, providing a clear path toward industrial scale-up.

Hub Target Addressed 
Diversifying domestic REE supply chain and minimizing generation of hazardous waste.
 

Post Masters and Post Doctorate fellows Willow Hasley-Velez (back) and Elizabeth Garcia (front) collect samples of LREE and HREE concentrates and purified organic solvent
Post Masters and Post Doctorate fellows Willow Hasley-Velez (back) and Elizabeth Garcia (front) collect samples of LREE and HREE concentrates and purified organic solvent.