| Title | UV-visible spectroscopy of macrocyclic alkyl, nitrosyl and halide complexes of cobalt and rhodium. Experiment and calculation |
| Publication Type | Journal Article |
| Year of Publication | 2015 |
| Authors | Hull, EA, West, AC, Pestovsky, O, Kristian, KE, Ellern, A, Dunne, JF, Carraher, JM, Bakac, A, Windus, TL |
| Journal | Dalton Transactions |
| Volume | 44 |
| Pagination | 3811-3816 |
| Date Published | 02 |
| Type of Article | Article |
| ISBN Number | 1477-9226 |
| Accession Number | WOS:000349668200036 |
| Keywords | crystal-structure, model |
| Abstract | xes involve transitions from M-X bonding orbitals and/or metal d orbitals to M-X antibonding orbitals. In contrast, complexes with X = Cl or NO2 exhibit only d-d bands in the visible, so that homolytic cleavage of the M-X bond requires UV photolysis. UV-Vis spectra are not significantly dependent on the structure of the equatorial ligands, as shown by similar spectral features for (NH3)(5)CoCH32+ and L-1(H2O)CoCH32+. |
| DOI | 10.1039/c4dt03143a |
| Custom 1 | 3D Catalysis |
| Custom 2 | Chemical Physics |
