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Unconventional Clathrates with Transition Metal-Phosphorus Frameworks

TitleUnconventional Clathrates with Transition Metal-Phosphorus Frameworks
Publication TypeJournal Article
Year of Publication2018
AuthorsWang, J, Dolyniuk, JA, Kovnir, K
JournalAccounts of Chemical Research
Volume51
Pagination31-39
Date Published01
Type of ArticleReview
ISBN Number0001-4842
Accession NumberWOS:000423252900005
Keywordschemistry, compound, computer-search, crystal-structure, cu, frank-kasper structures, physical-properties, silicon, solid-state, space fullerenes, thermoelectric properties
Abstract

five and six-coordinated, and all metal atoms are joined in Cu-Zn. dumbbells. Our work shows that unconventional clathrates exhibit diverse crystal structures,and unique chemical bonding, which result in tunable transport properties. While they are similar to their tetra, counterparts in some.ways, they are very different in others. Specifically, the high thermal,and chemical stabilities and low thermal conductivities, of unconventional dathrates, make thein promising Bases for fiirther development of thermoelectric materials.

DOI10.1021/acs.accounts.7b00469
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