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A Three-Dimensional Microporous Metal Metalloporphyrin Framework

TitleA Three-Dimensional Microporous Metal Metalloporphyrin Framework
Publication TypeJournal Article
Year of Publication2015
AuthorsGuo, ZY, Yan, D, Wang, HL, Tesfagaber, D, Li, XL, Chen, YS, Huang, WK, Chen, BL
JournalInorganic Chemistry
Volume54
Pagination200-204
Date Published01
Type of ArticleArticle
ISBN Number0020-1669
Accession NumberWOS:000347506500027
Keywordsadsorption, efficient, energy-transfer, hydrogen storage, ligand, linker, organic frameworks, porphyrin, topology, water
Abstract

A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)(2)(H2O)(4)]}center dot(DEF)(20)center dot(CH3OH)(18)center dot(H2O)(12) (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 angstrom. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.

DOI10.1021/ic502116k
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