|Title||Surface Organometallic Chemistry of Supported Iridium(III) as a Probe for Organotransition Metal-Support Interactions in C-H Activation|
|Publication Type||Journal Article|
|Year of Publication||2018|
|Authors||Kaphan, DM, Klet, RC, Perras, FA, Pruski, M, Yang, C, Kropf, AJ, Delferro, M|
|Type of Article||Article|
|Keywords||100-percent, active-sites, arene hydrogenation, c-h activation, chemistry, dynamic, enhanced nmr-spectroscopy, ethylene polymerization, Heterogeneous catalysis, hydride complexes, nuclear-polarization, polymerization catalysts, selective propane dehydrogenation, site heterogeneous catalysts, solid-state nmr, sulfated oxides, sulfated zirconia, surface organometallic catalysis|
rd electrophilic bond activation of both sp(2) and sp3 C-H bonds, including the rapid deuteration of methane at room temperature; however, the global trend for the supports studied here does not suggest a direct correlation between activity and surface Bronsted acidity.
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