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Surface Organometallic Chemistry of Supported Iridium(III) as a Probe for Organotransition Metal-Support Interactions in C-H Activation

TitleSurface Organometallic Chemistry of Supported Iridium(III) as a Probe for Organotransition Metal-Support Interactions in C-H Activation
Publication TypeJournal Article
Year of Publication2018
AuthorsKaphan, DM, Klet, RC, Perras, FA, Pruski, M, Yang, C, Kropf, AJ, Delferro, M
JournalAcs Catalysis
Volume8
Pagination5363-5373
Date Published06
Type of ArticleArticle
ISBN Number2155-5435
Accession NumberWOS:000434369600064
Keywords100-percent, active-sites, arene hydrogenation, c-h activation, chemistry, dynamic, enhanced nmr-spectroscopy, ethylene polymerization, Heterogeneous catalysis, hydride complexes, nuclear-polarization, polymerization catalysts, selective propane dehydrogenation, site heterogeneous catalysts, solid-state nmr, sulfated oxides, sulfated zirconia, surface organometallic catalysis
Abstract

rd electrophilic bond activation of both sp(2) and sp3 C-H bonds, including the rapid deuteration of methane at room temperature; however, the global trend for the supports studied here does not suggest a direct correlation between activity and surface Bronsted acidity.

DOI10.1021/acscatal.8b00855
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3D Catalysis