You are here

Studies of minute quantities of natural abundance molecules using 2D heteronuclear correlation spectroscopy under 100 kHz MAS

TitleStudies of minute quantities of natural abundance molecules using 2D heteronuclear correlation spectroscopy under 100 kHz MAS
Publication TypeJournal Article
Year of Publication2015
AuthorsNishiyama, Y, Kobayashi, T, Malon, M, Singappuli-Arachchige, D, Slowing, II, Pruski, M
JournalSolid State Nuclear Magnetic Resonance
Volume66-67
Pagination56-61
Date Published04
Type of ArticleArticle
ISBN Number0926-2040
Accession NumberWOS:000351665800010
Keywordsangle-spinning nmr, cross-polarization, functionalized, HMQC, HSQC, Indirect detection, mesoporous silica, mesoporous silicas, n-15 nmr, nanoparticles, protein, proton, rotating solids, sensitivity enhancement, solid-state nmr, ultra-fast mas, ultrafast MAS
Abstract

r volume. The benefits of ultrafast MAS in such experiments include superior resolution in H-1 dimension without resorting to H-1-H-1 homonuclear RE decoupling, easy optimization, and applicability to mass-limited samples. The HMQC spectra of surface-bound species can be also acquired under 100 kHz MAS, although the dephasing of transverse magnetization has significant effect on the efficiency transfer under MAS alone. Published by Elsevier Inc.

DOI10.1016/j.ssnmr.2015.02.001
Custom 1

3D Catalysis