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Structural and magnetic properties of Ti4+/Co2+ co-substituted cobalt ferrite

TitleStructural and magnetic properties of Ti4+/Co2+ co-substituted cobalt ferrite
Publication TypeJournal Article
Year of Publication2014
AuthorsNlebedim, IC, Dennis, KW, McCallum, RW, Jiles, DC
JournalJournal of Applied Physics
Date Published05
Type of ArticleArticle
ISBN Number0021-8979
Accession NumberWOS:000335643700064

The variations in the structural magnetic properties of cobalt ferrite due to Ti4+/Co2+ co-substitution for 2Fe(3+) are presented. The non-linear relation in the variation of the lattice parameter agrees with a previous study on cation distribution, which showed that the rate of substitution of cations into the A-sites and B-sites varies with Ti-concentration. Such variation in the rate of substitution into the cation sites was also observed in the magnetization, coercive field, and susceptibility data. The coercive field and differential susceptibility are inversely related. Although the coercive field of the Ti-substituted cobalt ferrite generally decreased compared to the un-substituted cobalt ferrite, magnetic susceptibility was higher at higher Ti-concentrations. (C) 2014 AIP Publishing LLC.

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