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Stability of Pd nanoparticles on carbon-coated supports under hydrothermal conditions

TitleStability of Pd nanoparticles on carbon-coated supports under hydrothermal conditions
Publication TypeJournal Article
Year of Publication2018
AuthorsHuo, JJ, Johnson, RL, Duan, P, Pham, HN, Mendivelso-Perez, D, Smith, EA, Datye, AK, Schmidt-Rohr, K, Shanks, BH
Journal Technology
Volume8
Pagination1151-1160
Date Published02
Type of ArticleArticle
ISBN Number2044-4753
Accession NumberWOS:000427152800022
Keywordsaqueous-phase, Biomass, chemistry, conversion, deactivation, hydrogenation, liquid, ruthenium catalysts, stable heterogeneous catalysts, surface groups, water
Abstract

Hydrothermal stability is one of the major challenges facing heterogeneous catalysis in biomass conversion to chemicals or fuels. Though carbon supports have shown better hydrothermal stability than common metal oxide supports like alumina and silica, improving the stability of metal nanoparticles supported on carbon still remains a challenge. In this work, carbon-coated SBA-15 (mesoporous silica) materials in which thin carbon overlayers were pyrolyzed at 300, 400, and 600 degrees C giving different surface chemistries, as quantitatively verified by C-13 NMR and XPS. As the pyrolysis temperature increased, the carbon overlayer had fewer oxygen functional groups and more aromatic groups. After depositing Pd nanoparticles on the support, hydrothermal treatments and aqueous-phase furfural hydrogenation were used to test the catalyst stability. Better Pd dispersion and enhanced hydrothermal stability were observed when Pd was supported on the carbon-coated SBA-15 pyrolyzed at lower temperature.

DOI10.1039/c7cy02098h
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