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Solid-state coexistence of {Zr-12} and {Zr-6} zirconium oxocarboxylate clusters

TitleSolid-state coexistence of {Zr-12} and {Zr-6} zirconium oxocarboxylate clusters
Publication TypeJournal Article
Year of Publication2014
AuthorsMalaestean, IL, Alici, MK, Besson, C, Ellern, A, Kogerler, P
JournalCrystengcomm
Volume16
Pagination43-46
Date Published01
Type of ArticleArticle
ISBN Number1466-8033
Accession NumberWOS:000327606900008
Keywordszr6o4(oh)(4)(oocr)(12)
Abstract

Ligand metathesis, Co(II) coordination, and partial condensation reactions of an archetypal {Zr-6} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks {Zr6O8} and {Zr12O22}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the {Zr6O8}-based product.

DOI10.1039/c3ce41829d
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