Title | Single crystal growth from light, volatile and reactive materials using lithium and calcium flux |
Publication Type | Journal Article |
Year of Publication | 2014 |
Authors | Jesche, A, Canfield, PC |
Journal | Philosophical Magazine |
Volume | 94 |
Pagination | 2372-2402 |
Date Published | 05 |
Type of Article | Article |
ISBN Number | 1478-6435 |
Accession Number | WOS:000337978400002 |
Keywords | alloys, Crystal growth, dicalcium nitride, ferromagnetism, hydride, Intermetallic compounds, Magnetic, ni, nitrides, phase, properties, solution growth, system, transition, X-ray diffraction, y2ni7 |
Abstract | We present a method for the solution growth of single crystals from reactive Li and Ca melts and its application to the synthesis of several, representative compounds. Among these, single crystalline Li3N, Li-2(Li1-xTx) N with T = {Mn, Fe, Co}, LiCaN, Li2C2, LiRh and LiIr from Li-rich flux, as well as Ca2N, CaNi2, CaNi3, YbNi2, Y2Ni7 and LaNi5 from Ca-rich flux could be obtained. Special emphasize is given on the growth of nitrides using commercially available Li3N and Ca3N2 powders as the nitrogen source instead of N-2 gas. |
DOI | 10.1080/14786435.2014.913114 |
Custom 1 | Complex States |