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Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl

TitleRapid and ordered carbonylation and oxygenation of a cobalt(II) methyl
Publication TypeJournal Article
Year of Publication2017
AuthorsReinig, RR, Fought, EL, Ellern, A, Windus, TL, Sadow, AD
JournalChemical Communications
Volume53
Pagination11020-11023
Date Published10
Type of ArticleArticle
ISBN Number1359-7345
Accession NumberWOS:000412410700009
Keywordsalkyl, bearing, chemistry, co, co(ii), complexes, fe, geometry, hydride, ligands, spin-state
Abstract

The oxidative carbonylation of To(M)CoMe (1; To(M) = tris(4,4-dimethyl-2-oxazolinyl) phenylborate) involves its rapid, reversible reaction with CO to form To(M)Co{C(O) Me} CO (2) followed by rapid reaction with O-2 yielding To(M)CoOAc (3), in contrast to the slow direct carboxylation of To(M)CoMe by CO2.

DOI10.1039/c7cc06339c
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3D Catalysis