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Platinum Nanoparticle Decorated SiO2 Microfibers as Catalysts for Micro Unmanned Underwater Vehicle Propulsion

TitlePlatinum Nanoparticle Decorated SiO2 Microfibers as Catalysts for Micro Unmanned Underwater Vehicle Propulsion
Publication TypeJournal Article
Year of Publication2016
AuthorsChen, BL, Garland, NT, Geder, J, Pruessner, M, Mootz, E, Cargill, A, Leners, A, Vokshi, G, Davis, J, Burns, W, Daniele, MA, Kogot, J, Medintz, IL, Claussen, JC
Journal Interfaces
Volume8
Pagination30941-30947
Date Published11
Type of ArticleArticle
ISBN Number1944-8244
Accession NumberWOS:000388429600032
Keywordsdecomposition, hydrogen, hydrogen-peroxide, Materials Science, metal nanoparticles, micro unmanned underwater vehicles, microengines, motion, motors, nanotubes, oxidation, peroxide, platinum nanoparticles, propulsion, reduction, silicon microfibers, systems, Technology - Other Topics
Abstract

Micro unmanned underwater vehicles (UUVs) need to house propulsion mechanisms that are small in size but sufficiently powerful to deliver on-demand acceleration for tight radius turns, burst-driven docking maneuvers, and low speed course corrections. Recently, small-scale hydrogen peroxide (H2O2) propulsion mechanisms have shown great promise in delivering pulsatile thrust for such acceleration needs. However, the need for robust, high surface area nanocatalysts that can be manufactured on a large scale for integration into micro UUV reaction chambers is still needed. In this report, a thermal/electrical insulator, silicon oxide (SiO2) microfibers, is used as a support for platinum nanoparticle (PtNP) catalysts. The mercapto-silanization of the SiO2 microfibers enables strong covalent attachment with PtNPs, and the resultant PtNP SiO2 fibers act as a robust, high surface area catalyst for H2O2 decomposition. The PtNP SiO2 catalysts are fitted inside a micro UUV reaction chamber for vehicular propulsion; the catalysts can propel a micro UUV for 5.9 m at a velocity of 1.18 m/s with 50 mL of 50% (w/w) H2O2. The concomitance of facile fabrication, economic and scalable processing, and high performance including a reduction in H2O2 decomposition activation energy of 40-50% over conventional material catalysts paves the way for using these nanostructured microfibers in modern, small-scale underwater vehicle propulsion systems.

DOI10.1021/acsami.6b10047
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Alternate JournalACS Appl. Mater. Interfaces