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Open-Framework Manganese(II) and Cobalt(II) Borophosphates with Helical Chains: Structures, Magnetic, and Luminescent Properties

TitleOpen-Framework Manganese(II) and Cobalt(II) Borophosphates with Helical Chains: Structures, Magnetic, and Luminescent Properties
Publication TypeJournal Article
Year of Publication2017
AuthorsLi, M, Smetana, V, Wilk-Kozubek, M, Mudryk, Y, Alammar, T, Pecharsky, VK, Mudring, AV
JournalInorganic Chemistry
Volume56
Pagination11104-11112
Date Published09
Type of ArticleArticle
ISBN Number0020-1669
Accession NumberWOS:000411549400031
Keywordsaluminophosphate, anionic partial structure, chemistry, crystal-structure, dot h2o, hydrothermal synthesis, ionothermal synthesis, metal phosphates, microcrystal diffraction, molecular-sieves, tetrahedral framework
Abstract

at 77 K. Both compounds are Curie-Weiss paramagnets with negative Weiss constants and effective magnetic moments expected for noninteracting Mn2+ and Co2+ cations but no clear long-range magnetic order above 2 K.

DOI10.1021/acs.inorgchem.7b01423
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