You are here

Metal-Organic-Framework-Derived Carbons: Applications as Solid-Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis

TitleMetal-Organic-Framework-Derived Carbons: Applications as Solid-Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis
Publication TypeJournal Article
Year of Publication2017
AuthorsLi, XL, Zhang, BY, Fang, YH, Sun, WJ, Qi, ZY, Pei, YC, Qi, SY, Yuan, PY, Luan, XC, Goh, TW, Huang, WK
JournalChemistry-a European Journal
Volume23
Pagination4266-4270
Date Published03
Type of ArticleArticle
ISBN Number0947-6539
Accession NumberWOS:000399314800005
Keywordsammonia borane, aromatic frameworks, cascade, catalysts, chemistry, dehydrogenation, doped porous carbon, efficient, heterogeneous, hydrogenation reactions, Knoevenagel condensation, knoevenagel condensation-reactions, metal-organic frameworks, mof, n-doped carbons, palladium, reactions, tandem catalysis
Abstract

The facile pyrolysis of a bipyridyl metal-organic framework, MOF-253, produces N-doped porous carbons (Cz-MOF-253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen-containing MOF-derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz-MOF-253-supported Pd nanoparticles (Pd/Cz-MOF- 253-800) show excellent performance in a one-pot sequential Knoevenagel condensation-hydrogenation reaction.

DOI10.1002/chem.201605852
Custom 1

Royalty

Short TitleChem.-Eur. J.
Alternate JournalChem.-Eur. J.