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Mechanism of Solid-State Thermolysis of Ammonia Borane: A N-15 NMR Study Using Fast Magic-Angle Spinning and Dynamic Nuclear Polarization

TitleMechanism of Solid-State Thermolysis of Ammonia Borane: A N-15 NMR Study Using Fast Magic-Angle Spinning and Dynamic Nuclear Polarization
Publication TypeJournal Article
Year of Publication2014
AuthorsKobayashi, T, Gupta, S, Caporini, MA, Pecharsky, VK, Pruski, M
JournalJournal of Physical Chemistry C
Volume118
Pagination19548-19555
Date Published08
Type of ArticleArticle
ISBN Number1932-7447
Accession NumberWOS:000341122200005
Keywordsboron-nitride, chemical hydrogen storage, complex hydrides, high-frequency, mas-nmr, n-h compounds, sensitivity enhancement, Spectroscopy, spent fuel, thermal-decomposition
Abstract

manner, which then transform directly into hexagonal boron nitride analog through the dehydrocyclization reaction, bypassing the formation of polyiminoborane.

DOI10.1021/jp504328x
Custom 1

Complex Hydrides