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Ionothermal Synthesis, Crystal Structure, and Magnetic Study of Co2PO4OH Isostructural with Caminite

TitleIonothermal Synthesis, Crystal Structure, and Magnetic Study of Co2PO4OH Isostructural with Caminite
Publication TypeJournal Article
Year of Publication2014
AuthorsWang, GM, Valldor, M, Spielberg, ET, Mudring, AV
JournalInorganic Chemistry
Volume53
Pagination3072-3077
Date Published03
Type of ArticleArticle
ISBN Number0020-1669
Accession NumberWOS:000333142800040
Keywordschemistry, co, composites, framework cobalt phosphate, hydrogen-bonds, Ionic liquids, minerals, nanoparticles
Abstract

= 2/3). Phosphate tetrahedra groups interconnect four rod-packed face-sharing (1)(infinity){CoO6/2} octahedra chains to form a three-dimensional framework structure. The compound Co2PO4OH was further characterized by powder X-ray diffraction, Fourier transform-infrared, and ultraviolet-visible spectroscopy, confirming the discussed structure. The magnetic measurement reveals that Co2PO4OH undergoes a magnetic transition and presents at low temperatures a canted antiferromagnetic spin order in the ground state.

DOI10.1021/ic4029904
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