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Intermolecular beta-Hydrogen Abstraction in Ytterbium, Calcium, and Potassium Tris(dimethylsilyl)methyl Compounds

TitleIntermolecular beta-Hydrogen Abstraction in Ytterbium, Calcium, and Potassium Tris(dimethylsilyl)methyl Compounds
Publication TypeJournal Article
Year of Publication2013
AuthorsYan, K, Schoendorff, G, Upton, BM, Ellern, A, Windus, TL, Sadow, AD
JournalOrganometallics
Volume32
Pagination1300-1316
Date Published03
Type of ArticleArticle
ISBN Number0276-7333
Accession NumberWOS:000316094900020
Keywordsagostic rigidity, aluminum complexes, ansa-lanthanidocene complexes, benzyl complexes, crystal-structures, organometallic compounds, structural-characterization, tetrahydrofuran adduct, thermal-decomposition, x-ray structures
Abstract

h3 to give beta-H abstracted products. The compounds M{C(SiHMe2)(3)}(2)THF2 react with SiMe3I to yield Me3SiH and disilacyclobutane as the products of beta-H abstraction, while M{C(SiHMe2)(3)}(2)TMEDA and Me3SiI form a mixture of Me3SiH and the alkylation product Me3SiC(SiHMe2)(3) in a 1:3 ratio.

DOI10.1021/om3010299
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Chemical Physics

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