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Impact of Linker Engineering on the Catalytic Activity of Metal-Organic Frameworks Containing Pd(II)-Bipyridine Complexes

TitleImpact of Linker Engineering on the Catalytic Activity of Metal-Organic Frameworks Containing Pd(II)-Bipyridine Complexes
Publication TypeJournal Article
Year of Publication2016
AuthorsLi, XL, Van Zeeland, R, Maligal-Ganesh, RV, Pei, YC, Power, G, Stanley, L, Huang, WK
JournalAcs Catalysis
Volume6
Pagination6324-6328
Date Published09
Type of ArticleArticle
ISBN Number2155-5435
Accession NumberWOS:000382714000079
Keywords-bipyridine, bipyridyl linker, chemistry, coupling reactions, Heterogeneous catalysis, highly efficient, isoreticular metal-organic frameworks, ligands, nanoparticles, relationship, robust, single-site catalyst, stability, structure-activity, suzuki reaction, Suzuki-Miyaura cross-coupling, transformations, water
Abstract

-Me(2)bpy-MOE-PdCl2, respectively. This result clearly demonstrates that the stereoelectronic properties of metal-binding linker units are critical to the activity of single-site organometallic catalysts in MOFs and highlights the importance of linker engineering in the design and development of efficient MOF catalysts.

DOI10.1021/acscatal.6b01753
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Alternate JournalACS Catal.