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An Icosahedral Quasicrystal and Its 1/0 Crystalline Approximant in the Ca-Au-Al System

TitleAn Icosahedral Quasicrystal and Its 1/0 Crystalline Approximant in the Ca-Au-Al System
Publication TypeJournal Article
Year of Publication2016
AuthorsPham, J, Kreyssig, A, Goldman, AI, Miller, GJ
JournalInorganic Chemistry
Volume55
Pagination10425-10437
Date Published10
Type of ArticleArticle
ISBN Number0020-1669
Accession NumberWOS:000385785700057
Keywordsalloys, approximant, cell, chemistry, Crystallography, cubic, electronic-structure, Intermetallic compounds, periodic crystals, phases, visualization, yb
Abstract

= 0.31(1)] as polar intermetallic species, whereby Ca atoms engage in polar covalent bonding with the electronegative, electron-deficient [Au3-xAl1+x] tetrahedral clusters and the observed phase width of the crystalline approximant.

DOI10.1021/acs.inorgchem.6b01636
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Alternate JournalInorg. Chem.