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Homoleptic Trivalent Tris(alkyl) Rare Earth Compounds

TitleHomoleptic Trivalent Tris(alkyl) Rare Earth Compounds
Publication TypeJournal Article
Year of Publication2017
AuthorsPindwal, A, Yan, KK, Patnaik, S, Schmidt, BM, Ellern, A, ,, Bae, C, Sadow, AD
JournalJournal of the American Chemical Society
Volume139
Pagination16862-16874
Date Published11
Type of ArticleArticle
ISBN Number0002-7863
Accession NumberWOS:000416496400060
Keywordsagostic, alkyl complexes, ansa-lanthanidocene complexes, chemistry, interactions, metal, molecular-structures, organolanthanide complexes, polymerization catalysis, si-h interactions, structural-characterization, surface organometallic chemistry, x-ray crystal
Abstract

- HSi/SiH exchange involves rotation of a single C(SiHMe2)(3) ligand that is coordinated to the Ln center through the Ln-C bond and one secondary interaction. These robust organometallic compounds persist in solution and in the solid state up to 80 degrees C, providing potential for their use in a range of synthetic applications. For example, reactions of Ln{C(SiHMe2)(3)}(3) and ancillary proligands, such as bis-1,1-(4,4-dimethyl-2-oxazolinyl)ethane (HMeC(Ox(Me2))(2)) give {MeC(Ox(Me2))(2)}Ln{C(SiHMe2)(3)}(2), and reactions with disilazanes provide solvent-free lanthanoid tris(disilazides).

DOI10.1021/jacs.7b09521
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