You are here

Eu2P7X and Ba2As7X (X = Br, I): Chiral double-Zintl salts containing heptapnictotricyclane clusters

TitleEu2P7X and Ba2As7X (X = Br, I): Chiral double-Zintl salts containing heptapnictotricyclane clusters
Publication TypeJournal Article
Year of Publication2018
AuthorsDolyniuk, JA, Lee, S, Tran, N, Wang, J, Wang, LL, Kovnir, K
JournalJournal of Solid State Chemistry
Volume263
Pagination195-202
Date Published07
Type of ArticleArticle
ISBN Number0022-4596
Accession NumberWOS:000433525000027
Keywordschemistry, Chiral structure, clathrate-iii, compound, crystal-structure, electronic-structures, phosphides, Pnictide, double Zintl salts, electronic structure, polar, polyphosphides, structural chemistry, thermoelectric properties
Abstract

ons and halogen anions. Band structure calculations predict semiconducting properties for all synthesized compounds. Diffuse reflectance UV-vis spectroscopy indicates that Eu2P7I is a direct bandgap semiconductor with E-g of 1.7 eV.

DOI10.1016/j.jssc.2018.04.026
Custom 1

Not AL