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Escape of anions from geminate recombination in THF due to charge delocalization

TitleEscape of anions from geminate recombination in THF due to charge delocalization
Publication TypeJournal Article
Year of Publication2017
AuthorsChen, HC, Cook, AR, Asaoka, S, Boschen, JS, Windus, TL, Miller, JR
JournalPhysical Chemistry Chemical Physics
Volume19
Pagination32272-32285
Date Published12
Type of ArticleArticle
ISBN Number1463-9076
Accession NumberWOS:000417958900010
Keywordschemistry, debye-smoluchowski equation, dissociation, field-assisted, inverted region, nonadiabatic, photoinduced electron-transfer, physics, picosecond, polar environment, proton, proton-transfer reactions, pulse-radiolysis, radical-ion-pairs, solvated electron
Abstract

free ions with escape rate constants near 3 x 10(6) s(-1). These experiments find no evidence for an inverted region for proton transfer.

DOI10.1039/c7cp05880b
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