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Enhancing the Sensitivity of Solid-State NMR Experiments with Very Low Gyromagnetic Ratio Nuclei with Fast Magic Angle Spinning and Proton Detection

TitleEnhancing the Sensitivity of Solid-State NMR Experiments with Very Low Gyromagnetic Ratio Nuclei with Fast Magic Angle Spinning and Proton Detection
Publication TypeJournal Article
Year of Publication2018
AuthorsVenkatesh, A, Ryan, MJ, Biswas, A, Boteju, KC, Sadow, AD, Rossini, AJ
JournalJournal of Physical Chemistry A
Volume122
Pagination5635-5643
Date Published06
Type of ArticleArticle
ISBN Number1089-5639
Accession NumberWOS:000437811100016
Keywordschemistry, cp mas, cross-polarization, fast, integer quadrupolar nuclei, inverse detection, low-gamma, magnetic-resonance-spectroscopy, mas, nuclei, physics, rotating solids, simpson, spectra
Abstract

h of the material required to fill a 4 mm rotor. Fast MAS and proton detection were applied to obtain (89)gamma and Rh-103 solid-state NMR spectra of organometallic complexes. These results demonstrate that proton detection and fast MAS represents a general approach to enable and accelerate solid-state NMR experiments with very low-gamma nuclei.

DOI10.1021/acs.jpca.8b05107
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3D Catalysis

Alternate JournalJ. Phys. Chem. A