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Combined measurement of directional Raman scattering and surface-plasmon-polariton cone from adsorbates on smooth planar gold surfaces

TitleCombined measurement of directional Raman scattering and surface-plasmon-polariton cone from adsorbates on smooth planar gold surfaces
Publication TypeJournal Article
Year of Publication2018
AuthorsNyamekye, CKA, Weibel, SC, Bobbitt, JM, Smith, EA
JournalAnalyst
Volume143
Pagination400-408
Date Published01
Type of ArticleArticle
ISBN Number0003-2654
Accession NumberWOS:000422641200005
Keywordsangle, chemistry, coupled emission, resonance measurements, sensor chip, Spectroscopy, spr, thickness, thin-films, total-reflection, wave
Abstract

e angle of the incident laser under total internal reflection. The collected parameters on the prism side of the interface include a full surface-plasmon-polariton cone and the full Raman signal radiating from the cone as a function of incident angle. An instrument for performing directional RS and a quantitative study of the instrumental parameters are herein reported. To test the sensitivity and quantify the instrument parameters, self-assembled monolayers and 10 to 100 nm polymer films are studied. The signals are found to be well-modeled by two calculated angle-dependent parameters: three-dimensional finite-difference time-domain calculations of the electric field generated in the sample layer and projected to the far-field, and Fresnel calculations of the reflected light intensity. This is the first report of the quantitative study of the full surface-plasmon-polariton cone intensity, cone diameter, and directional Raman signal as a function of incident angle. We propose that directional RS is a viable alternative to surface plasmon resonance when added chemical information is beneficial.

DOI10.1039/c7an01299c
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3D Catalysis