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Benzene Selectivity in Competitive Arene Hydrogenation: Effects of Single-Site Catalyst center dot center dot center dot Acidic Oxide Surface Binding Geometry

TitleBenzene Selectivity in Competitive Arene Hydrogenation: Effects of Single-Site Catalyst center dot center dot center dot Acidic Oxide Surface Binding Geometry
Publication TypeJournal Article
Year of Publication2015
AuthorsGu, WX, Stalzer, MM, Nicholas, CP, Bhattacharyya, A, Motta, A, Gallagher, JR, Zhang, GH, Miller, JT, Kobayashi, T, Pruski, M, Delferro, M, Marks, TJ
JournalJournal of the American Chemical Society
Volume137
Pagination6770-6780
Date Published06
Type of ArticleArticle
ISBN Number0002-7863
Accession NumberWOS:000355890600012
Keywords100-percent active-sites, chemistry, correlation nmr-spectroscopy, ethylene polymerization, functionalized mesoporous, heterogeneous catalysts, low-temperature hydrogenolysis, olefin polymerization catalysts, organometallic, silicas, solid-state nmr, sulfated zirconia
Abstract

metal center-anionic sulfated oxide surface distances, and this separation/weakened ion-pairing enables the activation/insertion of more sterically encumbered arenes and influences hydrogenation rates and selectivity patterns.

DOI10.1021/jacs.5b03254
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3D Catalysis