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1D SbSeI, SbSI, and SbSBr With High Stability and Novel Properties for Microelectronic, Optoelectronic, and Thermoelectric Applications

Title1D SbSeI, SbSI, and SbSBr With High Stability and Novel Properties for Microelectronic, Optoelectronic, and Thermoelectric Applications
Publication TypeJournal Article
Year of Publication2018
AuthorsPeng, B, Xu, K, Zhang, H, Ning, ZY, Shao, HZ, Ni, G, Li, J, Zhu, YY, Zhu, HY, Soukoulis, CM
JournalAdvanced Theory and Simulations
Volume1
Pagination1700005
Date Published01
Type of ArticleArticle
ISBN Number2513-0390
Accession NumberWOS:000449746300004
Keywordscarbon nanotube, carrier mobility, channel materials, constant, dft calculations, electron-hole excitations, field-effect transistors, nanowires, one-dimensional materials, optical-properties, prediction, SbSBr, SbSeI, SbSI, semiconductor, Technology - Other Topics, thermoelectric performance, transitions
Abstract

Mechanical exfoliation of 2D materials has triggered an explosive interest in low dimensional material research. We extend this idea to 1D van der-Waals materials. Three 1D semiconductors (SbSel, SbSI, and SbSBr) with high stability and novel electronic properties are discovered using first principles calculations. Both the dynamical and the thermal stability of these 1D materials are examined. We demonstrate that their nanowire thinner than 7 A can be easily obtained by mechanical exfoliation, hydrothermal method, or sonochemical method. The bulk-to-1D transition results in dramatic changes in band gap, effective mass, and static dielectric constant due to quantum confinement, making 1D SbSel a highly promising channel material for transistors with gate length shorter than 1 nm. Under small uniaxial strain, these materials are transformed from indirect into direct band gap semiconductors, paving the way for optoelectronic devices and mechanical sensors. Moreover, the thermoelectric performance of these materials is significantly improved over their bulk counterparts. These highly desirable properties render SbSel, SbSI, and SbSBr promising 1D materials for applications in future microelectronics, optoelectronics, mechanical sensors, and thermoelectrics.

DOI10.1002/adts.201700005
Custom 1

Metamaterials

Short TitleAdv. Theory Simul.
Alternate JournalAdv. Theory Simul.