Characteristic Features of the Sorption-Desorption of Hydrogen by Mg-M-Ni (M = Al, Mn, Ti) Ternary Alloys

TitleCharacteristic Features of the Sorption-Desorption of Hydrogen by Mg-M-Ni (M = Al, Mn, Ti) Ternary Alloys
Publication TypeJournal Article
Year of Publication2013
AuthorsBerezovets VV, Denys RV, Zavalii IY, Paul-Boncour V, Pecharsky V
Journal TitleMaterials Science
Volume49
Pages159-169
Date Published09
Type of ArticleArticle
ISBN Number1068-820X
Accession NumberWOS:000328207600003
KeywordsHYDRIDE, hydrides, hydrogen, MAGNESIUM ALLOYS, magnesium compounds, mg2feh6, storage, system
Abstract

By the method of high-energy milling in a ball mill, we obtain new alloys of Mg-M-Ni (M = Al, Mn, Ti) ternary systems. The properties of hydrogen sorption of the Mg3AlNi2 compound (Ti2Ni-type structure) are investigated and compared with the properties of Mg3MNi2 (M = Mn, Ti) isostructural compounds. The sorption-desorption of hydrogen by Mg(88)M4Ni(8) (M = Al, Mn, Ti) alloys is studied. The catalytic influence of Mg3MNi2 ternary phases on the hydrogenation of magnesium is established.

URL<Go to ISI>://WOS:000328207600003
DOI10.1007/s11003-013-9595-1