Probing Quadrupolar Nuclei by Solid-State NMR Spectroscopy: Recent Advances

TitleProbing Quadrupolar Nuclei by Solid-State NMR Spectroscopy: Recent Advances
Publication TypeBook Chapter
Year of Publication2012
AuthorsFernandez C, Pruski M
EditorChan JCC
Book TitleSolid State NMR
CityBerlin
PublisherSpringer-Verlag Berlin
Volume306
Pages119-188
Series TitleTopics in Current Chemistry
ISBN Number0340-1022978-3-642-24803-0
Accession NumberWOS:000305579100005
Keywords(HETCOR), angle-spinning nmr, coherences, cross-polarization, DETECTION, Double rotation (DOR), double-rotation nmr, Dynamic angle spinning (DAS), ECHO DOUBLE-RESONANCE, experiments, Half-integer spin quadrupolar nuclei, half-integer-spin, Heteronuclear correlation, heteronuclear dipolar interactions, High-resolution methods, high-resolution nmr, homonuclear correlation, Homonuclear recoupling, hyperbolic secant pulses, Indirect, Integer spin nuclei, j-coupling, magnetic-resonance-spectroscopy, Multiple-quantum magic angle, NUCLEI, QUADRUPOLAR, Quadrupolar echo, Quadrupolar interaction, quantum cross-polarization, Satellite transition magic angle spinning (STMAS), Selection of, sensitivity enhancement, solid-state nmr, spinning (MQMAS)
Abstract

Solid-state nuclear magnetic resonance (NMR) of quadrupolar nuclei has recently undergone remarkable development of capabilities for obtaining structural and dynamic information at the molecular level. This review summarizes the key achievements attained during the last couple of decades in solid-state NMR of both integer spin and half-integer spin quadrupolar nuclei. We provide a concise description of the first- and second-order quadrupolar interactions, and their effect on the static and magic angle spinning (MAS) spectra. Methods are explained for efficient excitation of single-and multiple-quantum coherences, and acquisition of spectra under low- and high-resolution conditions. Most of all, we present a coherent, comparative description of the high-resolution methods for half-integer quadrupolar nuclei, including double rotation (DOR), dynamic angle spinning (DAS), multiple-quantum magic angle spinning (MQMAS), and satellite transition magic angle spinning (STMAS). Also highlighted are methods for processing and analysis of the spectra. Finally, we review methods for probing the heteronuclear and homonuclear correlations between the quadrupolar nuclei and their quadrupolar or spin-1/2 neighbors.

URL<Go to ISI>://WOS:000305579100005
DOI10.1007/128_2011_141
AbbreviationTop. Curr. Chem.