A polyoxometalate-based manganese carboxylate cluster

TitleA polyoxometalate-based manganese carboxylate cluster
Publication TypeJournal Article
Year of Publication2008
AuthorsFang XK, Kogerler P
Journal TitleChemical Communications
Pages3396-3398
Type of ArticleArticle
ISBN Number1359-7345
Accession NumberISI:000257722700013
Keywordscatalysis, elements, HIGH-SPIN, METAL-LANTHANIDE COMPLEXES, molecules, OXIDATION-STATES, POLYOXOANIONS, SINGLE-MOLECULE MAGNETS, surfaces
Abstract

The functionalization of a pre-formed, high oxidation state {(CeMn6IV)-Mn-IV} cluster with a lacunary phosphotungstate, [alpha-P2W15O56](12-), exemplifies a straightforward route for grafting redox-active building blocks to existing Mn-carboxylate clusters and modeling their deposition onto metal oxide surfaces.

DOI10.1039/b804111c
Alternate JournalChem. Commun.