Photonic Systems


Project Leader(s):
Joseph Shinar

Principal Investigators:
Rana Biswas, Kai-Ming Ho, Joseph Shinar, Costas Soukoulis


The goal of this project is to learn to control the flow of light and the conversion of light energy into other forms of energy (and vice versa). This project is fundamental physics research that supports the mission of DOE in the areas of energy-efficient lighting, efficient solar energy utilization, and thermophotovoltaics. Research in this Project can be grouped into two sub-tasks.

Photonic Crystal Physics
Photonic band gap materials are artificially designed periodic dielectric or metallic structures with high refractive-index contrast that can be used to control light (photons) in a manner similar to that used by semiconductors to control electrons. Although this research project originated from theoretical work, its emphasis now is on physical manifestations and tests of the theory. Over the next three years research goals within this subtask will focus on:

  • Wide area fabrication of photonic crystal and polymer waveguide structures using reasonable-cost soft lithography techniques (K. Constant, W. Leung, K.-M. Ho).
  • Study of fundamental photonic crystal properties including tailored thermal emission, beam steering and focusing (R. Biswas, K. Constant, C. Soukoulis, W. Leung, K.-M. Ho).
  • Development of highly efficient algorithms for design and study of devices using photonic crystals. Extension of techniques to study non-linear systems or systems with gain as well as the effects of disorder/fabrication defects on the performance of photonic crystal structures. (C. Soukoulis, K.-M. Ho)

Organic Semiconductor Physics
The goal of this subtask is to provide the fundamental physics underpinning necessary to understand and optimize the performance of organic light-emitting devices (OLEDs) at both low and high brightness. More specifically, the goal is to elucidate the interactions (particularly the spin-dependent interactions) between singlet excitons (SEs), triplet excitons (TEs), polarons, bipolarons, and trions, as they impact the optical and transport properties of these materials and devices. For example, our past experimental work has revealed the central role of TEs and polarons in quenching the SEs, thus decreasing the photoluminescence quantum yield of the films and the internal quantum efficiency of OLEDs. Indeed, these quenching processes are now recognized as the source of the decreasing efficiency of OLEDs at high injection current.

Over the next three years research within this subtask will focus on fundamental studies on novel OLED structures, including n-stacked (tandem) OLEDs, graded junction OLEDs, and hybrid polymer/small molecular OLEDs. (J. Shinar).


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Xiao T; Cui W P; Cai M; Liu R; Anderegg J W; Shinar J; Shinar R . 2012. Thin air-plasma-treated alkali fluoride layers for improved hole extraction in copper phthalocyanine/C-70-based solar cells. Journal of Photonics for Energy. 2:021006. abstract
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Cai M; Xiao T; Chen Y; Hellerich E; Liu R; Shinar R; Shinar J . 2011. Effect of molecular weight on the efficiency of poly(N-vinylcarbazole)-based polymer light-emitting diodes. Applied Physics Letters. 99:203302. abstract
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Liu R; Ye Z; Park J M; Cai M; Chen Y; Ho K M; Shinar R; Shinar J . 2011. Microporous phase-separated films of polymer blends for enhanced outcoupling of light from OLEDs. Optics Express. 19:A1272-A1280. abstract
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Mike J F; Intemann J J; Cai M; Xiao T; Shinar R; Shinar J; Jeffries-El M . 2011. Efficient synthesis of benzobisazole terpolymers containing thiophene and fluorene. Polymer Chemistry. 2:2299-2305. abstract
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Cai M; Xiao T; Liu R; Chen Y; Shinar R; Shinar J . 2011. Indium-tin-oxide-free tris(8-hydroxyquinoline) Al organic light-emitting diodes with 80% enhanced power efficiency. Applied Physics Letters. 99:153303. abstract
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Soukoulis C M; Wegener M . 2011. Past achievements and future challenges in the development of three-dimensional photonic metamaterials. Nature Photonics. 5:523-530. abstract
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Cui W P; Liu R; Smith A; Shinar J; Shinar R . 2011. Luminescence Decay Times of PdOEP:PVK OLEDs Fabricated in Controlled O(2) and H(2)O Environments. Organic Semiconductors in Sensors and Bioelectronics IV. 8118:81180v. abstract
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Cai M; Xiao T; Hellerich E; Chen Y; Shinar R; Shinar J . 2011. High-Efficiency Solution-Processed Small Molecule Electrophosphorescent Organic Light-Emitting Diodes. Advanced Materials. 23:3590-3596. abstract
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Liu R; Xu C; Biswas R; Shinar J; Shinar R . 2011. MoO(3) as combined hole injection layer and tapered spacer in combinatorial multicolor microcavity organic light emitting diodes. Applied Physics Letters. 99:093305. abstract
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Liu N; Lu N; Yao Y X; Li Y R; Wang C Z; Ho K M . 2011. Strain Effects in Ge/Si and Si/Ge Core/Shell Nanowires. Journal of Physical Chemistry C. 115:15739-15742. abstract
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