Solid-state coexistence of {Zr-12} and {Zr-6} zirconium oxocarboxylate clusters

TitleSolid-state coexistence of {Zr-12} and {Zr-6} zirconium oxocarboxylate clusters
Publication TypeJournal Article
Year of Publication2014
AuthorsMalaestean IL, Alici MK, Besson C, Ellern A, Kogerler P
Journal TitleCrystengcomm
Volume16
Pages43-46
Date Published01
Type of ArticleArticle
ISBN Number1466-8033
Accession NumberWOS:000327606900008
Keywordszr6o4(oh)(4)(oocr)(12)
Abstract

Ligand metathesis, Co(II) coordination, and partial condensation reactions of an archetypal {Zr-6} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks {Zr6O8} and {Zr12O22}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the {Zr6O8}-based product.

URL<Go to ISI>://WOS:000327606900008
DOI10.1039/c3ce41829d