Plasmonic Behavior of Single Gold Dumbbells and Simple Dumbbell Geometries

TitlePlasmonic Behavior of Single Gold Dumbbells and Simple Dumbbell Geometries
Publication TypeJournal Article
Year of Publication2013
AuthorsStender AS, Wei XZ, Augspurger AE, Fang N
Journal TitleJournal of Physical Chemistry C
Volume117
Pages16195-16202
Date Published08
Type of ArticleArticle
ISBN Number1932-7447
Accession NumberWOS:000323082300040
Keywordsgrowth, interference contrast microscopy, nanodumbbells, nanoparticles, nanorods, orientation sensors, regime, resonances, shape, spectroscopy
Abstract

Dumbbell-shaped nanoparticles are similar in size to their nanorod counterparts, but their optical properties have not been studied as extensively as the nanorod. In this paper, the spectra of a single dumbbell, several dumbbell dimers, and a pentamer were collected experimentally and compared with simulated spectra. Surface charge density plots were also obtained in order to elucidate the nature of the plasmonic modes. The dumbbell is shown to be a particle that acts as a transition from the nanorod to the nanosphere. Because the dumbbell shape allows adjacent particles to interlock like puzzle pieces, dumbbells can be thought of as optical building blocks that can combine into designs that are capable of supporting localized hot spots, Fano resonance, and tunable plasmon peaks.

URL<Go to ISI>://WOS:000323082300040
DOI10.1021/jp406064h